Yes, the keyboard will work with PCs. I'm not sure about the media keys, though. There is a piece of software for this, input remapper. It's designed mostly for macbook and macbook pro keyboards, but it will help with this. Especially because the order of ctrl win alt keys is different on the mac keyboard, you can rearange their keymap with input remapper, fixing this. Because it's designed for macbooks, and not standard PCs, set a restore point before installing just in case.
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